The way it works is there are several forms of pvp(player versus player). GvG (guild versus guild) is the highest form of pvp, in my opinion, followed by HA(heros ascent). Anyways, GvG is a match where two teams of 8 players fight with the ultimate goal of killing the Guild Lord. Reading the links that Jonas had will help you more than 90% of the people on guru.
Daily GvG can mean two things, Guilds often recruit for daily GvG which simply means they plan on GvGing every day. Daily GvG Tournaments also exist. These consist of several teams that battle random opponents. The tournies have several rounds and take a lot of time.
Sadly, GuildWars has been around for a long time and is relatively dead as compared to its past state. It is hard to get into any good form of pvp, let alone become good at it. You are facing players that have been pvping for years, it is simply unfair for newcomers. But Good Luck.
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