After my painful vanquish of Deldrimor Bowl and Anvil Rock, where I used EVSS abusively, I can assure you that only casters die on the proc (centaur monks in my situation). If :
boss's health > wars/rangers/etc health > casters' health,
then I'm 100% certain that you can't 1 shot a boss with EVSS. Though you could "nuke and run" repeatedly a boss without health regen... But as the above poster said, the proc is so abysmally low that it wouldn't be of much use.
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