All attribute points invested in skills from the old secondary class are removed and re-enter your attribute point pool, at no cost in refund points.
The skills available for each secondary class are kept track of separately on a per-character basis. Suppose you are a Mo/W with skills A, B, and C for warrior and skills D and E for mesmer. When you switch to Mo/Me, you can use skills D and E, and when you switch back to Mo/W, you will still have skills A, B, and C available.
Profession-specific quests that were unavailable during your first play-through will now become available, and these generally give you skills from your new secondary profession, but quests that you have already completed will not become re-enabled, and to acquire those skills would require either capturing them from a boss or buying them from a skill trainer.
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