For the most part, it's only your elite that changes in the common Domination bar for PvP. This is mainly speaking from a GvG point of view, though, and I'm not completely up-to-date with the meta, so don't take my word 100%.
Diversion
Shame
Shatter Enchantment
Drain Enchantment
Power Leak
Power Drain
-Elite-
-Res-
The elite is often Energy Surge, Power Block and Visions of Regret.
The res is often Flesh of my Flesh.
For PvE? If you're looking for efficiency, there are only a few skills that would be useful to an extent; single target shut down is rarely effective unless it makes a major impact (for example, daze allows every party member to interrupt). Cry of Frustration, Cry of Pain, Blackout and Arcane Conundrum are these skills. I don't necessarily touch the on-attack skills, but I guess Empathy, VoR and Backfire could be quite strong in the PvE enviroment. Clumsiness and Wandering Eye are also pretty good.
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