Recall the name of a file that was in that My Documents folder. Run a search on the C: drive for that file. When it comes up on the result list, right-click on it and an option for "Open Containing Folder" should appear. There should be that file, and all the files with it.
I'm for the idea of not installing Windows over Windows. Usually if a person is at that stage it is much more beneficial to format and install fresh. Computers simply need a format every so often anyway as junk builds up over time. However I would always have an independant O/S partition, and a 'storage' partition where you keep all your files. Or at the very least can copy all your files to in the event of a reformat.
Even better - multiple HDDs. Or one step further, RAIDs. Okay, I'm getting out of scope now...
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